The toxic ingredient in toad venom is called bufotenine, which is burned off while smoking. After the toxic stuff is gone, what’s left is the hallucinogen 5-MeO-DMT. THIS is what sends you to never-never land.
In order to get a smokeable sample, put the toad on a piece of glass (a pyrex baking dish works well) and rub the parotid glands behind it’s eyes. This will irritate the toad, and it will secrete a milky fluid. Once there is a goodly amount of it, let it evaporate to a crystal and then scrape it with a razor blade and place it in a glass pipe for smoking.
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